Chromium-manganese alloys on ochobi iron with increased tribological properties
Keywords:
Semiconductor silicon, complex doping, interaction energy, phase transformations, dislocation density, twins, magnetic field treatment, microhardness, specific electrical resistivity, charge minority-carrier lifetimeSynopsis
In this work, the rational compositions of the chemical composition of established and substantiated chromium-manganese alloys in the following ranges were: С = 2.6–3.0%; Cr = 10.0–20.0%; Mn = 10.0–15.0%; Ni = 0.5–1.7%; Si ≤ 1.3%; V ≤ 0.3%; Cu ≤ 0.3%.
It has been determined that an additional increase in the complex of properties of chromium-manganese alloys can be achieved by the additional introduction of molybdenum, titanium, barium and calcium in small amounts.
The peculiarities of the formation of the structure, phase composition and properties of the investigated chromium-manganese alloys in the cast state were. The change in the temperature intervals of the beginning and end of melting/crystallisation of alloys with different alloying systems was determined by thermal analysis. A comparative analysis of the melting/crystallisation temperature intervals revealed that the developed chromium-manganese alloys are characterised by lower energy consumption of the production process, and, therefore, are more technologically advanced in terms of achieving the required superheat temperature, subsequent casting into moulds and crystallisation.
According to the results of comparative tests for friction wear (temperature up to 950°C, load 500 N) and abrasive wear of chromium-manganese alloys with traditional analogue alloys in the cast state, it was found that the experimental material containing 3.10% C 13.10% Cr; 15.75% Mn; 1.15%Ni; 0.90% Si.
References
Glazov, V. M., Timoshina, G. G., Mikhailova, M. S. (1996). Printcipy legirovaniia kremniia dlia povysheniia ego termostabilnosti. Doklady Akademii Nauk, 347 (3), 352–355.
Taran, Yu. N., Glazov, V. M., Regel, A. R., Kutsova, V. Z., Koltsov, V. B., Timoshina, G. G. et al. (1991). Strukturnye prevrashcheniia pri nagreve monokristallov kremniia Fizika i tekhnika poluprovodnikov, 4 (25), 588–595.
Kol’tsov, V. B., Zubkov, A. M., Timoshina, M. I. (2002). Metodika issledovaniy elektrofizicheskikh svoystv monokristallov kremniya v shirokom intervale temperatur. Fizika poluprovodnikov i polumetallov. Saint-Petersburg.
Kozhitov, L. V., Botavin, V. V., Shepel, P. N., Timoshina, G. G., Timoshina, M. I. (2002). Issledovanie kinetiki raspada kremniia, legirovannogo perekhodnymi i redkozemelnymi elementami. Kremniy-2002. Novosibirsk, 129.
Novokhatskiy, I. A., Kisun’ko, V. Z., Ladyanov, V. I. (1985). Osobennosti proiavlenii razlichnykh tipov strukturnykh prevrashchenii v metallicheskikh rasplavakh. Izvestiya vuzov. Chernaya metallurgiya, 5, 1–9.
Kutsova, V. Z., Nosko, O. A., Timoshina, M. I. (2006). Alloying effect on structure and properties of semiconductor silicon. Proceeding of the International Conference Silicon 2006, 450–459.
Tonkov, E. Yu. (1988). Fazovye prevrashcheniia soedinenii pri vysokom davlenii. Vol. 1, 2. Moscow: Metallurgiya, 463, 356.
Kutsova, V. Z., Nosko, O. A., Timoshina, M. I. (2007). Vliianie legiruiushchikh elementov na strukturu, fazovyi sostav i svoistva poluprovodnikovogo kremniia. Kremniy-2007. Moscow: Gosudarstvennyy tekhnologicheskiy universitet “Moskovskiy institut stali i splavov”, 109.
Glazov, V. M., Zemskov, B. S. (1967). Fiziko-khimicheskie osnovy legirovaniia poluprovodnikov. Moscow: Nauka, 372.
Klevan, O. S., Engh, T. A. (1995). Dissolved impurities and inclusions in FeSi and Si, development of a filter sampler. INFACON 7. Trondheim, 441–451.
Prikhodko, E. V. (1983). Metallokhimiia kompleksnogo legirovaniia. Moscow: Metallurgiya, 184.
Nesterenko, A. M., Uzlov, K. I., Kutsova, V. Z., Nyshchenko, A. N. (1988). Vliianie skorosti okhlazhdeniia na obrazovanie tverdykh rastvorov v sisteme Al-Si. Izvestiya AN SSSR, Metally, 2, 192.
Savitskiy, E. M., Burkhanov, S. S. (1967). Metallovedenie tugoplavkikh metallov i splavov. Moscow: Nauka, 324.
Liubov, B. Ia. (1969). Kineticheskaia teoriia fazovykh prevrashchenii. Moscow: Metallurgiia, 264.
Taran, Yu. N., Kutsova, V. Z., Uzlov, K. I., Falkevich, E. S. (1992). Shearing phase transformations in semiconductors. Proceeding of the International Conference ‘Silicon 92’, 88–95.
Milvidskiy, M. G., Osvenskiy, V. B. (1984). Strukturnye defekty v monokristallakh poluprovodnikov. Moscow: Metallurgiya, 256.
Glazov, V. M., Koltsov, V. B., Kutsova, V. Z., Taran, Yu. N., Timoshina, G. G., Uzlov, K. I., Falkevich, E. S. (1990). Issledovanie elektro-fizicheskikh svoystv kremniya v shirokom intervale temperatur. Elektronnaya tekhnika, 11.
Glazov, V. M., Kurbatov, V. A., Koltsov, V. B. (1985). Issledovanie effekta Kholla antimonidov Ga i In v tverdom i zhidkom sostoyanii. Fizika i tekhnika poluprovodnikov, 19 (4), 662–667.
Kopaev, Iu. V., Meniailenko, V. V., Molotkov, S. N. (1985). Neravnovesnye fazovye perekhody v kovalentnykh poluprovodnikakh pod vozdeistviem lazernogo izlucheniia. Fizika tverdogo tela, 27 (11), 3288–3294.
Landau, L. D., Lifshits, E. M. (1964). Statisticheskaia fizika. Moscow: Nauka, 568.
Tairov, Yu. M., Tsvetkov, V. F. (1980). Rost kristallov i politipizm karbida kremniya. Rost kristallov, 13, 104–111.
Taran, Yu. N., Kutsova, V. Z., Chervonyy, I. F., Shvets, E. Ya., Falkevich, E. S. (2004). Poluprovodnikovyy kremniy: teoriya i tekhnologiya proizvodstva. Zaporozhe: Zaporozhskaya gosudarstvennaya inzhenernaya akademiya, 344.
Alshits, V. I., Darinskaya, E. V., Koldaeva, M. V., Petrzhik, E. A.; Hirth, J. P. (Ed.) (2008). Magnetoplastic Effect in Nonmagnetic Crystals. Dislocations in solids. Amsterdam: Elsevier, 14 (86), 333–437. https://doi.org/10.1016/s1572-4859(07)00006-x
Alshits, V. I., Darinskaya, E. V., Koldaeva, M. V., Petrzhik, E. A. (2003). Magnetoplastic effect: Basic properties and physical mechanisms. Crystallography Reports, 48 (5), 768–795. https://doi.org/10.1134/1.1612598
Golovin, Yu. I. (2004). Magnitoplastichnost tverdykh tel (Obzor). Fizika Tverdogo Tela, 46, 769.
Morgunov, R. B. (2004). Spinovaia mikromekhanika v fizike plastichnosti. Uspekhi fizicheskikh nauk, 174, 131–153.
Buchachenko, A. L. (2013). Mass-Independent Isotope Effects. The Journal of Physical Chemistry B, 117 (8), 2231–2238. https://doi.org/10.1021/jp308727w
Zinenko, V. N., Sorokin, B. P., Turchin, P. P. (1983). Osnovy fiziki tverdogo tela. Moscow: Vysshaia shkola, 330.
Milnes, A. G., Feuch, D. L. (1972). Heterojunctions and Metall-Semiconductor Junctions. New York; London: Academic Press, 418. https://doi.org/10.1016/b978-0-12-498050-1.x5001-6
Zhitinskaya, M. K., Nemov, S. A., Svechnikova, T. E. (1997). Vliyanie neodnorodnostey kristallov Bi2Te3 na poperechnyy effekt Nernsta – Ettingsgauzena. Fizika i tekhnika poluprovodnikov, 31 (4), 441–443.
Chervonyi, I. F., Kutsova, V. Z., Pozhuiev, V. I., Shvets, Ye. Ya., Nosko, O. A., Yehorov, S. H., Voliar, R. M. (2009). Napіvprovіdnikovyi kremnіi: teorіia і tekhnolohіia vyrobnytstva. Zaporіzhzhia, 350.
Vapnik, V. N. (Ed.) (1984). Algoritmy i programma vosstanovleniya zavisimostey. Moscow: Nauka, 816.
Kutsova, V. Z., Nosko, O. A., Tutyk, V. A., Sulay, A. M. (2015). Struktura, mekhanichni ta elektrofizychni vlastyvosti monokrystalichnoho kremniiu pid diieiu postiinoho mahnitnoho polia. Metallurgicheskaya i gornorudnaya promyshlennost, 1, 73–79.
Kutsova, V. Z., Nosko, O. A., Sulay, A. M. (2014). Vliianie legirovaniia i termicheskoi obrabotki na strukturu i svoistva poluprovodnikovogo kremniia. Metallurgicheskaya i gornorudnaya promyshlennost, 6, 65–72.
Kutsova, V. Z., Nosko, O. A., Sulay, A. M. (2015). The structure, mechanical and electrophysical properties of monocrystalline silicon under influence of constant magnetic field. Ukrainian journal of mechanical engineering and materials science, 1 (1), 91–98.
Kutsova, V. Z., Nosko, O. A., Sulai, A. M. (2017). The influence of constant magnetic field on the structure and properties of monocrystalline silicon. Metaloznavstvo ta termichna obrobka metaliv, 2, 32–40.
Bonch-Bruevich, V. P., Kalashnikov, S. G. (1990). Fizika poluprovodnikov. Moscow: Nauka, 685.
Moss, T. S., Burrell, G. J., Ellis, B. (1973). Semiconductor opto-electronics. Butterworth-Heinemann, 441. https://doi.org/10.1016/c2013-0-04197-7
Kutsova, V. Z., Uzlov, K. Y., Khronenko, V. M. (1999). Temperaturnaya zavisimost’ otnositel’nogo udlineniya sverkhchistogo kremniya. Metallurgicheskaya i gornorudnaya promyshlennost, 4, 72–74.
Taran, Iu. N., Kutcova, V. Z., Kovalchuk, M. G., Uzlov, K. I. (1988). Neodnorodnost beta-tverdogo rastvora v siluminakh. Metallovedenie i termicheskaia obrabotka metallov, 9, 33–37
Taran, Yu. N., Kutsova, V. Z. (2002). Fazovye prevrashcheniya i svoystva poluprovodnikovogo kremniya. Vysokochistye metallicheskie i poluprovodnikovye materialy. Kharkovskaya nauchnaya assambleya ISPM-8, 68–73.
Taran, Yu. M., Kutsova, V. Z., Nosko, O. A. (2002). Fazovi peretvorennia ta vlastyvosti napivprovidnykovoho kremniiu. Metaloznavstvo ta obrobka metalіv, 1–2, 59–65.
Taran, Yu. M., Kutsova, V. Z., Nosko, O. A. (2004). Semiconductor–Metal Phase Transitions. Uspehi Fiziki Metallov, 5 (1), 87–166. https://doi.org/10.15407/ufm.05.01.087
Kutsova, V. Z., Stetsenko, A. P., Mazochuk, V. F. (2017). Phase transformations in semiconductor silicon by the influence of magnetic field. Systemni tekhnolohii. Rehionalnyi mizhvuzivskyi zbirnyk naukovykh prats, 5 (112), 103–107.
Oranska, O. I., Gornikov, Yu. I., Gun’ko, V. M., Brichka, A. V. (2022). On the use of model diffraction profiles in the microstructure analysis of nanocrystalline metal oxides based on powder x-ray diffraction data. SURFACE, 14 (29), 148–158. https://doi.org/10.15407/surface.2022.14.148
Makara, V. A., Vasiliev, M. O., Steblenko, L. P., Koplak, O. V., Kuryliuk, A. M., Kobzar, Yu. L., Naumenko, S. M. (2009). Influence of Magnetic Treatment on the Microhardness and Surface Layers Structure of Silicon Crystals. Physics and Chemistry of Solid State, 10 (1), 193–198.
Nosko, O. A. (2006). Osobennosti struktury, fazovye prevrashcheniya legirovannogo kremniya i modifitsirovannykh zaevtekticheskikh siluminov i razrabotka sposobov povysheniya ikh svoystv [PhD dissertation]. Dnepropetrovsk, Ukraine.
Kutsova, V. Z. (1993). Teoriya i praktika upravleniya strukturoy i svoystvami liteynykh splavov na osnove alyuminiya i titana [Doctor's thesis]. Dnepropetrovsk, Ukraine.
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December 25, 2025
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Copyright (c) 2025 Maksym Kovzel, Oleksandr Babachenko, Daria Togobitska
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Kovzel, M., Babachenko, O., & Togobitska, D. (2025). Chromium-manganese alloys on ochobi iron with increased tribological properties. In I. Shalevska (Ed.), MODERN TRENDS IN CONSTRUCTION MATERIALS TECHNOLOGIES (pp. 3–51). Kharkiv: TECHNOLOGY CENTER PC. https://doi.org/10.15587/978-617-8360-17-7.ch1
